姚 远
地址:上海市徐汇区梅陇路130号实验一楼305室
电话:021-64252745,13801756073
E-mail: yaoyuan@ecust.edu.cn
教育经历
2005.4-2010.1 上海交通大学化学化工学院 理学博士(高分子化学与物理) 导师:颜德岳 教授,中国科学院院士
1998.9-2001.7 中国科学院化学研究所 理学硕士(高分子化学与物理) 导师:余云照 研究员
1994.9-1998.7 西安交通大学化学工程学院 工学学士(高分子材料)
工作经历
2016.1-至今 威廉希尔中文网站平台 讲师,副教授 (2017-)
2013.4-2014.4 伊利诺伊大学厄巴纳-香槟分校材料工程系 国家公派访问学者 合作导师:程建军 教授
2010.5-2016.1 上海交通大学化学化工学院化学系 助理研究员 课题组长:车顺爱 教授
2004.2-2005.4 上海应用技术学院 讲师
2001.7-2004.2 中国科学院化学研究所高技术材料研究室 助理研究员(2003.7-2014.2) 研究实习员(2001.7-2003.7)课题组长:赵彤 研究员
主持项目
(1)国家自然科学基金面上项目“交替聚合物定向自组装构筑长程有序精细纳米结构”。资助金额67.7万元。(2023.1-2026.12)
(2)国家自然科学基金面上项目“两亲聚乙炔基偶氮苯的光致多重响应与自组装研究”。资助金额71.6万元。(2021.1-2024.12)
(3)上海市自然科学基金面上项目“聚乙炔基偶氮苯光致动材料及其多重响应机制研究”。资助金额20万元。(2020.7-2023.6)
(4)国家自然科学基金面上项目“多重手性大分子的合成及多级手性自组装的研究”。资助金额73.2万元。(2016.1-2019.12)
(5)国家自然科学基金青年基金“基于可设计的嵌段聚合物模板制备有序介孔二氧化硅薄膜的研究”。资助金额24万元。(2012.1.1-2014.12.31)
(6)第50批教育部归国留学人员科研启动基金“基于多肽聚合物模板制备手性无机材料”。资助金额3万元。(2015.6-2017.6)
(7)上海交通大学高等学校新教师科研启动基金。资助金额8万元。(2011.6-2013.6)
子课题
(1)上海市基础重点项目“食品材料的组装与开发”,资助金额30万元。(2018.7-2021.7)
研究领域
1. 手性聚合物的合成及自组装
合成手性聚合物,研究其自组装行为,通过可控自组装构建多级(手性)结构。
2. 光响应聚合物
设计合成不同拓扑结构的光响应聚合物,研究其光致异构化、光致形变以及聚合物组装体的光响应行为,制备光致动器、光学防伪等新型材料。
3. 功能性介孔和大孔材料及模拟生物矿化(上海交通大学)
以小分子表面活性剂和多嵌段两亲性大分子为模板,制备介孔薄膜材料、介孔电极材料以及光子晶体材料。以聚氨基酸为模板,模拟生物矿化过程,制备手性无机纳米材料。
4. 特种热固性树脂(中国科学院化学研究所)
基于酚醛树脂骨架制备耐热、透波性良好的耐高温基体树脂,用于国防高技术领域。
讲授课程
(1)研究生专业课《近代高分子化学》,主要内容:聚合物合成新进展、复杂结构聚合物的设计与制备、大分子自组装、新功能聚合物的合成等。
(2)本科生基础课《材料概论》,主要内容:金属材料、无机非金属材料和高分子材料的基本知识。
(3)本科生实验课《高分子材料成型加工》,主要内容:聚合物材料的模压、挤出、吹塑、混炼、3D打印等加工技术。
发表文章、专利与专著
2022
[1] Zhenghui Liu, Yuan Yao*, Xinfeng Tao, Qixin Zhuang, Shaoliang Lin*, Helical supramolecular nanorods via sequential meticuloustailoring of noncovalent interaction and light irradiation, Science China Chemsitry 2022, 9, 1749-1757.
2021
[1] Rui Zhang*, Qionglong Fu, Di Zhu, Zheqi Shen, Keming Zhou, Yuan Yao*, Xuedong Zhu*, CO2-responsive spherical polyelectrolyte brush with multi-stimulation for reversible protein immobilization and release, Australian Journal of Chemistry 2021, 74, 135-144.
[2] Chen Tian, Kecong Zhou, Yufei Lu, Jinjie Li, Yuan Yao*, Xinfeng Tao, Qixin Zhuang, Yufeng Xie*, Shaoliang Lin*, Hyperbranched azopolymer with quadruple responsibility, Chinese Journal of Polymer Science 2021, 39, 1169-1176.
[3] Zhenghui Liu, Yuan Yao,* Xinfeng Tao, Jie Wei, Shaoliang Lin*. Helical self-assembly of amphiphilic chiral azobenzene alternating copolymers. ACS Macro Letters 2021, 10, 1174-1179.
[4] Dingfeng Shen, Yuan Yao,* Qixin Zhuang, Shaoliang Lin*.Mainchain alternating azopolymers with fast photo-induced reversible transition behavior, Macromolecules2021, 54, 10040-10048.
2020
[1] Rui Zhang*, Qionglong Fu, Keming Zhou, Yuan Yao*, Xuedong Zhu*, Ultra stretchable, tough and self-healable poly(acrylic acid) hydrogels cross-linked by self-enhanced high-density hydrogen bonds, Polymer 2020, 199, 122603.
[2] 毕伯威, 华启侠, 沈学宁, 潘泳康, 唐颂超*, 姚远*, 基于电荷相互作用的仿贻贝高性能黏合凝胶,英国威廉希尔唯一官网学报(自然科学)2020, 46, 488-494.
[3] Syed Asadullah, Shiqi Mei, Deqiang Wang, Yuan Yao, Yongkang Pan, Dongliang Wang*, Han Guo*, Jie Wei, Sulfonated porous surface of tantalum pentoxide/polyimide composite with micro-submicro structures displaying antibacterial performances and stimulating cell responses, Materials and Design 2020, 190, 108510.
[4] Hao Liu, Binbin Xu*, Xiaoyan Yang, Zhengyi Li, Zhe Mo, Yuan Yao, Shaoliang Lin*, Ultraviolet and infrared two-wavelength modulated self-healing materials based on azobenzene-functionalized carbon nanotubes, Composites Communications 2020, 19, 233-238.
[5] Jinjie Li, Jinhui Dong, Kun Cui, He Wang, Yao Sun, Yuan Yao, Jianzhuang Chen,* Jinlou Gu, Shaoliang Lin*, Pillararene-based supramolecular membranes with the rose-petal effect and nanostructure-modulated tunable water adhesion, Journal of Materials Chemistry A 2020, 8, 10917-10924.
[6] Zhengmin Tang, Zhanwen Xu, Chunhua Cai*, Jiaping Lin*, Yuan Yao, Chunming Yang, Xiaohui Tian, 2D chiral stripe nanopatterns self‐assembled from rod‐coil block copolymers on microstripes, Macromolecular Rapid Communications 2020, 41, 202000349.
[7] Zhengmin Tang, Da Li, Jiaping Lin*, Liangshun Zhang, Chunhua Cai*, Yuan Yao, Chunming Yang, Xiaohui Tian, Self-assembly of rod-coil block copolymers on a substrate into micrometer-scale ordered stripe nanopatterns, Polymer Chemistry 2020, 11, 7487-7496.
2019
[1] Rui Zhang, Hongwei Peng, Tianxu Zhou, Yuan Yao*, Xuedong Zhu, Bowei Bi, Xing Zhang, Binxiu Liu, Linyan Niu, Wenqing Wang, Constructing high performance hydrogels with strong underwater adhesion through a “mussel feet-rock” inspired strategy. ACS Applied Polymer Materials 2019, 1, 2883-2889.
[2] Jiacheng Wu, Binbin Xu, Zhenghui Liu, Yuan Yao*, Qixin Zhuang and Shaoliang Lin*, The synthesis, self-assembly and pH-responsive fluorescence enhancement of an alternating amphiphilic copolymer with azobenzene pendants. Polymer Chemistry 2019, 10, 4025-4030.
[3] Rui Zhang*, Tianxu Zhou, Hongwei Peng, Min Li, Xuedong Zhu* and Yuan Yao*, Nanostructured switchable pH-responsive membranes prepared via spherical polyelectrolyte brushes. Journal of Membrane Science 2019, 580, 117-124.
[4] Rui Zhang*, Hengzhi Ruan, Tianxu Zhou, Qionglong Fu, Xuedong Zhu* and Yuan Yao*, High-performance poly(acrylic acid) hydrogels formed with a block copolymer crosslinker containing amino-acid derivatives. Soft Matter 2019, 15, 7381-7389.
[5] Xiaofeng Niu, Yang Lin, Tianxu Zhou, Zhiwen Guan, Lixiao Liu, Xuhong Guo*, Yuan Yao*, Rui Zhang*, Nanoparticle capture by spherical polyelectrolyte brushes and its grading separation assisted by compressed CO2, Industrial and Engineering Chemistry Research 2019, DOI: 10.1021/acs.iecr.9b00140.
[6] Ling Jin, Yijing Wang, Tao Xue, Jing Xie, Yesheng Xu, Yuan Yao,* Xinxin Li*, Smart amphiphilic random copolymer-coated sponge with ph switchable wettability for on-demand oil/water separation, Langmuir 2019, 35, 14473-14480.
[7] Jinglin Wang, Chenshuo Shen, Songchao Tang*, Yuan Yao*, Study of charge-conjugated self-assembly behavior of amphiphilic block copolypeptides/helicene, Chinese Journal of Organic Chemistry 2019, 39, 2973-2979.
2018
[1]Liuying Sun, Fei Gao, Dingfeng Shen, Zhenghui Liu, Yuan Yao* and Shaoliang Lin*, Rationally designed hyperbranched azopolymer with temperature, photo and pH responsive behavior. Polymer Chemistry 2018, 9, 2977-2983.
[2] Xiaomei Gao, Fei Gao, Lingzhi Chen, Yuan Yao*, Tao Chen and Shaoliang Lin*. Tuning the morphology of amphiphilic copolymer aggregates by compound emulsifier via emulsion-solvent evaporation. Journal of Saudi Chemical Society 2018, 22, 297-305.
[3] Wei Wang, Dingfeng Shen, Xiao Li, Yuan Yao, Jiaping Lin, Aurelia Wang, Jiwoo Yu, Zhong Lin Wang, Suck Won Hong, Zhiqun Lin* and Shaoliang Lin*. Light-driven shape-memory porous films with precisely controlled dimensions. Angewandte Chemie International Edition 2018, 57, 2139-2143.
[4] Fei Gao, Yuan Yao, Wei Wang, Xiaofan Wang, Lei Li*, Qixin Zhuang and Shaoliang Lin*. Light-driven transformation of bio-inspired superhydrophobic structure via reconfigurable PAzoMA microarrays: from lotus leaf to rice leaf. Macromolecules 2018, 51, 2742-2749.
[5] Wei Wang, Fei Gao, Yuan Yao and Shaoliang Lin*. Directional photo-manipulation of self-assembly patterned microstructures. Chinese Journal of Polymer Science 2018, 36, 297-305.
[6] 王刚,张文凭,姚远,唐颂超,沈学宁*. 三嵌段聚乳酸在溶剂中结晶驱动自组装. 功能高分子学报,2018,4,已接收。
[7] 陈智,姚远,唐颂超*. 两亲刚性三嵌段聚多肽的合成及其自组装行为. 功能高分子学报,2018,3,20-27.
[8] 姚远,林绍梁*. 规整纳米结构的精确构筑:接枝共聚物的合成进展. 功能高分子学报,2018,1,16-19.
[9] Yuan Yao, Yongfeng Zhou and Deyue Yan*. Polypeptides synthesized by ring-opening polymerization of N-carboxyanhydrides: preparation, assembly and applications. The 11th Chapter of Bioinspired Materials Science and Engineering. John Wiley & Sons, New York, 2018, 201-223.
2017
[1] Xueli Kong, Xiaofan Wang, Tianchan Luo, Yuan Yao*, Lei Li and Shaoliang Lin*.Photomanipulated architecture and patterning of azopolymer array. ACS Applied Materials and Interfaces 2017, 9, 19345-19353.
[2] Rui Zhang*, Zhenchuan Yu, Lei Wang, Qizhe Shen, Xiaoyan Hou, Xuhong Guo, Junwei Wang, Xuedong Zhu* and Yuan Yao*. Chemistry-A European Journal 2017, 23, 13696-13703.
[3] Rui Zhang*, Lei Wang, Zheqi Shen, Min Li, Xuhong Guo* and Yuan Yao*. Ultrastretchable, tough, and notch-insensitive hydrogels formed with spherical polymer brush crosslinker. Macromolecular Rapid Communications 2017, 38, 1700455.
[4] Wei Wang, Yuan Yao, Tianchan Luo, Lingzhi Chen, Jiaping Lin*, Lei Li* and Shaoliang Lin*. Deterministic reshaping of breath figure arrays by directional photomanipulation. ACS Applied Materials and Interfaces 2017, 9, 4223-4230.
[5] Lingzhi Chen, Chen Tian, Yuan Yao and Shaoliang Lin*. Polymerization-induced self-assembly of P4VP-b-PBz
A copolymer in ethanol. Chinese Journal of Organic Chemistry 2017, 37, 2119-2123.
[6] Fei Gao, Yaohui Xing, Yuan Yao, Liuying Sun, Yao Sun, Xiaohua He* and Shaoliang Lin*. Self-assembly and multi-stimuli responsive behavior of PAA-b-PAzoMA-b-PNIPAM triblock copolymers. Polymer Chemistry 2017, 8, 7529-7536.
2016
[1] Yunlong Tan, Ke Zhang, Huiying Liao, Guyu Xiao*, YuanYao*, Guoming Sun, Deyue Yan. Trisulfonation approach: To improve the properties of poly(arylenethioether phosphineoxide)s based proton exchange membranes. Journal of Membrane Science 2016, 508, 32-39.
[2] Xin Cao, Dongpo Xu, Yuan Yao, Lu Han*, Osamu Terasaki and Shunai Che*. Chemistry of Materials 2016, 28, 3691-3702.
2015
[1] Yuan Yao and Chuanliang Feng*, Time-dependence mapping surface nano-structures of weak phase separated block copolymer film. Langmuir2015, 31, 9026−9032.
[2] Dongpo Xu, Zhehao Huang, Lu Han, Yuan Yao* and Shunai Che*, Amphiphilic ABC triblock terpolymer templated large-pore mesoporous silicas. Materials Letters 2015, 141, 176-179.
[3] Yuan Yao, Ji Feng, Lu Han* and Shunai Che, Hierarchal multi-lamellar silica vesicle clusters synthesized through self-assembly and mineralization. RSC Advances 2015, 5, 102256–102260.
[4] Dapeng Zhang, Yujiao Fan, Huimei Li, Ke Li, Yuan Yao*, Yongfeng Zhou* and Deyue Yan. A dumbbell-like supramolecular triblock copolymer and its self-assembly of light-responsive vesicles. RSC Advances 2015, 5, 47762-47765.
[5] Yingying Duan, Lu Han, Jialiang Zhang, Shunsuke Asahina, Zhehao Huang, Lin Shi, Bo Wang, Yuanyuan Cao, Yuan Yao, Liguo Ma, Cui Wang, Rina K. Dukor, Lu Sun, Chun Jiang, Zhiyong Tang, Laurence A. Nafie, and Shunai Che*. Angewandte Chemie International Edition 2015, 54, 15170-15175.
2014
[1] Dongpo Xu, Zhehao Huang, Rongrong Miao, Yitian Bie, Jun Yang,* Yuan Yao* and Shunai Che*. Rigid bolaform surfactant templated mesoporous silicon nanofibers as anode materials for lithiumion batteries. Journal of Materials Chemistry A 2014, 2, 19855-19860.
[2] Dongpo Xu, Yuan Yao,* Lu Han and Shunai Che. Molecular design of the amphiphilic AB diblock copolymer toward one-step synthesis of aminogroup functionalized large pore mesoporous silica. RSC Advances 2014, 4, 43047-43051.
[3] Lu Han, Dongpo Xu, Ye Liu, Tetsu Ohsuna, Yuan Yao, Chun Jiang,* Yiyong Mai, Yuanyuan Cao, Yingying Duan, and Shunai Che. Synthesis and characterization of macroporous photonic structure that consists of azimuthally shifted double-diamond silica frameworks. Chemistry of Materials2014, 26, 7020-7028.
[4] Huan Wang, Yuan Yao, Lu Han and Shunai Che. Amphiphilic ABC triblock terpolymer templating for mesoporous silica. Chemistry Research in Chinese Universities 2014, 30, 863-867.
[5] Zhehao Huang, Yuan Yao, Lu Han and Shunai Che*. Control of chiral nanostructures by self-assembly of designed amphiphilic peptides and silica biomineralization. Chemistry-A European Journal 2014, 20, 17068-17076.
[6] Zhehao Huang, Yuan Yao and Sh unai Che. Design of amphiphilic peptide geometry towards biomimetic self-assembly of chiral mesoporous silica. Chemistry-A European Journal 2014, 20, 3273-3276.
[7] Yingying Duan, Xiao Liu, Lu Han, Shunsuke Asahina, Dongdong Xu, Yuanyuan Cao, Yuan Yao, and Shunai Che*. Optically Active Chiral CuO “Nanoflowers”. Journal of American Chemistry Society 2014, 136, 7193-7196.
[8] Ben Liu, Lu Han, Yingying Duan, Yunayuan Cao, Ji Feng, Yuan Yao and Shunai Che. Growth of optically active chiral inorganic films through DNA self-assembly and silica mineralization. Scientific Reports 2014, 4, 4866.
2013
[1] Ji Feng, Bo Sun, Yuan Yao*and Shunai Che*. Silicone surfactant templated mesoporous silica. Microporous and Mesoporous Materials 2013, 172, 30-35.
[2] Yuan Yao, Dong Wang, Lu Han, and Shunai Che*. Self-assembly of α-helices to form rare two-dimensional square P4mm symmetry via silica mineralization. Chemistry-A European Journal 2013, 19, 15489-15492.
[3] Ben Liu, Yuan Yao, and Shunai Che*. Template-assisted self-assembly: alignment, placement, and arrangement of two-dimensional mesostructured DNA-silica platelets. Angewandte Chemie International Edition 2013, 52, 14186-14190.
[4] Ji Feng, Yuan Yao, LuHan, Bo Sun, Shaohua Liu, Zifeng Ma, Shunai Che*. Silicone surfactant templating for mesoporous silica@carbon complex. Microporous and Mesoporous Materials 2013, 174, 62-66.
[5] Bo Sun, Caiyun Guo, Yuan Yao, Zhehao Huang and Shunai Che. Journal of Materials Science 2013, 48, 1890-1898.
Before 2013
[1] Bo Sun, Caiyun Guo, Yuan Yao and Shunai Che*. Functional group-template integrated ABC copolymer silicone surfactant directing for highly hydrophobic mesoporous silica. Journal of Materials Chemistry 2012, 22, 19076-19080.
[2] Bo Sun, Caiyun Guo, Yuan Yao, Shunai Che. ABC copolymer silicone surfactant templating for biomimetic silicification. Journal of Colloid and Interface Science 2012, 378, 93-99.
[3] Chaozhong Ma, Lu Han, Zhang Jiang, Zhehao Huang, Ji Feng, Yuan Yao* and Shunai Che*. Growth of mesoporous silica film with vertical channels on substrate using gemini surfactants. Chemistry of Materials 2011, 23, 3583-3586.
[4] Wenyong Dong, Haixing Cheng, Yuan Yao, Yongfeng Zhou, Gangsheng Tong, Deyue Yan*, Yijian Lai and Wei Li. Bioinspired synthesis of calcium carbonate hollow spheres with a nacre-type laminated microstructure. Langmuir 2011, 27, 366-370.
[5] Jing Wang, Yuan Yao, Bing Ji, Wei Huang*, Yongfeng Zhou and Deyue Yan. The amphiphilic multiarm copolymers based on hyperbranched polyester and lysine: synthesis and self-assembly. Chinese Journal of Polymer Science 2011, 241-250.
[6] Qizhi Ren*, Yuan Yao, Xiaojian Ding, ZongSheng Hou and Deyue Yan*. Phase-transfer of porphyrins by polypeptide-containing hyperbranched polymers and a novel iron(III) porphyrin biomimetic catalyst. Chemical Communications 2009, 4732-4734.
[7] Bo Guo, Zengqian Shi, Yuan Yao, Yongfeng Zhou* and Deyue Yan*. Facile preparation of novel peptosomes through complex self-assembly of hyperbranched polyester and polypeptide. Langmuir 2009, 25, 6622-6626.
[8] Yuan Yao, Wenyong Dong, Shenmin Zhu, Xinhai Yu, and Deyue Yan*. Novel morphology of calcium carbonate controlled by poly(L-lysine). Langmuir 2009, 25, 13238-13243.
[9] Yuan Yao, Wenwen Li, Shoubai Wang, Deyue Yan* and Xuesi Chen*. Polypeptide modification of multiwalled carbon nanotubes by a graft-from approach. Macromolecular Rapid Communications 2006, 27, 2019-2025.
[10] Yuan Yao, Tong Zhao* and Yunzhao Yu. Novel thermosetting resin with a very high glass-transition temperature based on bismaleimide and allylated novolac. Journal of Applied Polymer Science 2005, 97, 443-448.
[11] Yuan Yao, Wei Huang, Ying Huang and Yunzhao Yu. Synthesis of alkoxysilanes bearing beta-diketone group through hydrosilylation. Chinese Chemical Letters 2002, 13, 121-124.
[12] Wei Huang*, Yuan Yao, Ying Huang and YunzhaoYu. Surface modification of epoxy resin by polyether–polydimethylsiloxanes–polyether triblock copolymers. Polymer 2001, 42, 1763-1766.
[13] ZL 03105746.2 姚远,赵彤,余云照。一种热固性树脂组合物及其制备方法 2008 国密2996。
[14] ZL03105747.0 姚远,赵彤,余云照。一种耐高温热固性树脂组合物及其制备方法 2008 国密2997。
[15] ZL03147830.1 姚远,余云照。一种硅橡胶组合物及其制备方法 2005 CN1566213A。